抄録
Offer Organization: Japan Society for the Promotion of Science, System Name: Grants-in-Aid for Scientific Research, Category: Grant-in-Aid for Scientific Research on Priority Areas, Fund Type: -, Overall Grant Amount: - (direct: 16600000, indirect: -)
We investigated the dynamics of molecules interacting with near-infrared intense laser pulses by using the time-dependent adiabatic state approach developed. The results for C60 indicate that the mode selectivity of vibrational excitation can be achieved by a pulse train, i.e., by changing the intervals between pulses. Time-dependent multiconfiguration theory is also developed to investigate the multielectron (ionization) dynamics of molecules. We have demonstrated that nuclear vibration is nonadiabatically coupled to the ring current of π electrons.