抄録
Offer Organization: Japan Society for the Promotion of Science, System Name: Grants-in-Aid for Scientific Research, Category: Grant-in-Aid for Young Scientists (B), Fund Type: -, Overall Grant Amount: - (direct: 3100000, indirect: 930000)
Focus has been directed for tin-based perovskite films as a substitute for most widely studied lead halide perovskites. This research has investigated the relationship between crystal growth control of tin-based perovskite along with defect analysis and its implications on the solar cell performance.
We have demonstrated a profound enhancement of the short circuit current from 20 mA/cm2 to 30 mA/cm2 using SnI2 complex for the fabrication of tin-halide perovskite as material. It has been found that when TiO2 as electron transporting material and SnI2 were chemically bonded, there was an increase in the TiO2 surface traps. Therefore, efforts were directed to prepare the tin-based perovskite solar cells without using TiO2 which led to the improved device performance. The absorption wavelength was changed by partially replacing the iodine by bromine. SnF2 was also doped in order to supplement metal defects. The conversion efficiency of the solar cell improved from 4.5% to 15.9%.